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(±)-1,1'-双(2-萘胺)
(±)-1,1'-Bi(2-naphthylamine)
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| 产品编号 | 包装单位 | 单价(元) | 国内现货 | 国外库存 | 询价单 |
| 3029635 | 1g | 2410 | |||
| 3029635 | 5g | 4980 |
产品别名
4488-22-6
(±)-1,1'-双(2-萘胺)
(±)-1,1'-Bi(2-naphthylamine)
(±)-1,1'-Binaphthyl-2,2'-diamine
(±)-BINAM
基本信息
| 应用 | Novel axially chiral Rh N-heterocyclic carbene complexes were prepared from axially dissymmetric 1,1?-binaphthalenyl-2,2?-diamine and applied in the Rh-catalyzed enantioselective hydrosilylation of methyl ketones. The enantioselective direct aldol reaction, organocatalyzed by recoverable BINAM- prolinamide derivatives can be highly accelerated by a catalytic amount of a carboxylic acid without a detrimental of the obtained enantioselectivities. |
| 备注 | Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents. |
| MDL | MFCD00145204 |
| 分子式 | C20H16N2 |
| 分子量 | 284.36 |
| 熔点 | 188-193° |
| 灵敏度 | Ambient temperatures. |
| 形态 | Powder |
| 溶解性 | Insoluble in water |
| 危险类别 | 22-41 Harmful if swallowed.Risk of serious damage to eyes. |
安全信息
| 安全等级 | 26-36/37/39-60 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.This material and its container must be disposed of as hazardous waste |
| RTECS | DU3090000 |
| 欧盟危险品标志 |  |
| TSCA | 否 |
GHS危害和防范说明
| GHS符号 |   |
| Hazard Statements | H302-H318 Harmful if swallowed.Causes serious eye damage. |
| Precautionary Statements | P280i-P264-P305+P351+P338-P310a-P301+P312a-P501a Wear eye/face protection.Wash thoroughly after handling.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Dispose of contents/container in accordance with local/regional/national/international regulations. |
