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(R)-(+)-2,2'-双(二-4-甲基苯基膦)-1,1'-联萘
(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl
产品价格查看更多规格...
| 产品编号 | 包装单位 | 单价(元) | 国内现货 | 国外库存 | 询价单 |
| 3029939 | 100mg | 581 | |||
| 3029939 | 0.5g | 2040 | |||
| 3029939 | 2g | 7430 | |||
| 3029939 | 10g | 16810 |
产品别名
99646-28-3
(R)-(+)-2,2'-双(二-4-甲基苯基膦)-1,1'-联萘
(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl
(R)-Tol-BINAP
基本信息
| 应用 | (R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl is used as chiral catalyst ligand. (R)-T-BINAP complexes derived from rhodium precursors are used for the asymmetric hydroformylation of vinyl acetate. It is a catalysts used for reductive amination of ketones, Pt dications for cation trapping, Rh(I)-catalyst for hydrogenation of acetamidoacrylic acid derivatives. |
| 备注 | Store in cool, dry place in tightly closed container. Store away from oxidizing agents. |
| MDL | MFCD00269856 |
| 分子式 | C48H40P2 |
| 分子量 | 678.79 |
| 熔点 | 255-257° |
| 灵敏度 | Ambient temperatures. |
| 形态 | Powder |
| 溶解性 | Insoluble in water. |
| 危险类别 | 36/37/38 Irritating to eyes, respiratory system and skin. |
安全信息
| 安全等级 | 26-37 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
| TSCA | 否 |
GHS危害和防范说明
| GHS符号 |  |
| Hazard Statements | H315-H319-H335 Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation. |
| Precautionary Statements | P261-P280a-P305+P351+P338-P304+P340-P405-P501a Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations. |
