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三氟甲烷磺酸铋(III)

Bismuth(III) trifluoromethanesulfonate
产品编号:3030111
规格:99%
CAS NO:88189-03-1
包装规格:5g,25g
产品类别:进口试剂
品牌:Alfa Aesar
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
30301115g719
303011125g2650
产品别名

88189-03-1

三氟甲烷磺酸铋(III)

Bismuth(III) trifluoromethanesulfonate

Bismuth triflate

Trifluoromethanesulfonic acid bismuth salt

基本信息
应用
Bismuth(III) trifluoromethanesulfonate acts as a catalyst in Friedel-Crafts acylation and cycloisomerization of allene-enol ethers. It behaves as a direct substitution catalyst and involved in the substitution of allylic, propargylic, and benzylic alcohols with sulfonamides, carboxamides and carbamates. Further, it is also used in Mukaiyama aldol reactions.
备注
Hygroscopic. Incompatible with strong oxidizing agents.
MDL
MFCD02093669
分子式
C3BiF9O9S3
分子量
656.19
熔点
>300°
灵敏度
Hygroscopic. Ambient temperatures.
形态
Powder
溶解性
Soluble in organics acetonitrile, dioxane, dimethyl formamide and dimethyl sulfoxide.
包装组
III
危险类别
34
Causes burns.
安全信息
危险等级
8
安全等级
26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
欧盟危险品标志
 
TSCA
GHS危害和防范说明
GHS符号
 
Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.
Precautionary Statements
P280-P303+P361+P353-P305+P351+P338-P310
Wear protective gloves/protective clothing/eye protection/face protection.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Immediately call a POISON CENTER or doctor/physician.
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