2-溴-2-甲基丙酰溴

2-Bromoisobutyryl bromide is used to prepare N-protected halodienamide, which provides four- and five-membered lactams in the presence of copper(I) and a tertiary amine. Further, it is used as atom transfer radical polymerization(ATRP) initiator for functionalization of hydroxyl groups present on the surface of graphene oxide. It is also used in preparation of polycaprolactone macroinitiators through reaction with oligomeric caprolactone diol and mesoporous silica nanoparticles with ATRP initiator anchored on the exterior surface.

Moisture sensitive. Incompatible with strong oxidizing agents and strong alkalis.

MFCD00000122

244-017-3

C₄H₆Br₂O

229.91

160-162°

>110°(230°F)

1.860

1.5095

Moisture Sensitive. Ambient temperatures.

Liquid

Miscible with acetone and carbon disulfide.

1746128

II

14-34
Reacts violently with water.Causes burns.

8

26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

 

是

 

H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.