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3-溴-1-三甲基硅烷-1-丙炔
3-Bromo-1-trimethylsilyl-1-propyne
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产品编号 | 包装单位 | 单价(元) | 国内现货 | 国外库存 | 询价单 |
3034364 | 5g | 1330 | |||
3034364 | 25g | 5880 |
产品别名
38002-45-8
3-溴-1-三甲基硅烷-1-丙炔
3-Bromo-1-trimethylsilyl-1-propyne
3-(Trimethylsilyl)propargyl bromide
基本信息
应用 | 3-Bromo-1-trimethylsilyl-1-propyne is used in the preparation of tetrahydroisoquinoline-3-carboxylic acid derivatives. It acts as a propargylating agent and used for the alkylation of dianion of beta-keto esters at gamma-carbon. It plays an important role in the synthesis of allenic alcohols and terminal conjugated enynes. |
备注 | Store in cool place. Incompatible with strong oxidizing agents. |
MDL | MFCD00134460 |
分子式 | C6H11BrSi |
分子量 | 191.14 |
沸点 | 44-45°/2mm |
闪点 | 63°(145°F) |
密度 | 1.17 |
折射率 | 1.483 |
灵敏度 | Ambient temperatures. |
形态 | Liquid |
溶解性 | Immiscible with water. |
Beilstein | 2037650 |
危险类别 | 36/37/38 Irritating to eyes, respiratory system and skin. |
安全信息
安全等级 | 26-37 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
TSCA | 否 |
GHS危害和防范说明
GHS符号 | |
Hazard Statements | H227-H315-H319-H335 Combustible liquid.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation. |
Precautionary Statements | P210e-P261-P280a-P305+P351+P338-P405-P501a Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations. |