乙酸钯(II)

Palladium(II) acetate is a catalyst of choice for a wide variety of reactions such as vinylation, Wacker process, Buchwald-Hartwig amination, carbonylation, oxidation, rearrangement of dienes (e.g., Cope rearrangement), C-C bond formation, reductive amination, etc. Precursor to Pd(0), other Pd(II) compounds of catalytic significance, and Pd nanowires.

Palladium(II) acetate decomposes to palladium on warming in alcoholic solutions, or on heating in other organic solvents. It is not compatible with strong oxidizing agents.

MFCD00012453

222-164-4

C₁₂H₁₈O₁₂Pd₃

673.46

ca 205° dec.

Ambient temperatures.

Powder

Soluble as monomer in glacial acetic acid or as trimer in benzene.

14,6991

41-43-53
Risk of serious damage to eyes.May cause sensitization by skin contact.May cause long-term adverse effects in the aquatic environment.

24-26-37/39-60-61
Avoid contact with skin.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable gloves and eye/face protection.This material and its container must be disposed of as hazardous wasteAvoid release to the environment. Refer to special instructions/safety data sheets.

AJ9000000

是

  

H318-H317-H413
Causes serious eye damage.May cause an allergic skin reaction.May cause long lasting harmful effects to aquatic life.

P261-P280a-P305+P351+P338-P310a-P321-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Specific treatment (see label).Dispose of contents/container in accordance with local/regional/national/international regulations.