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3-苯基丙酰氯
3-Phenylpropionyl Chloride
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| 产品编号 | 包装单位 | 单价(元) | 国内现货 | 国外库存 | 询价单 |
| 3057487 | 10g | 963 | |||
| 3057487 | 50g | 3210 | |||
| 3057487 | 250g | 16530 |
产品别名
645-45-4
3-苯基丙酰氯
3-Phenylpropionyl Chloride
Hydrocinnamoyl Chloride
基本信息
| 应用 | The 3-phenylpropionate (dihydrocinnamoyl) ester has been used as a protecting group in nucleoside synthesis. Used in the synthesis of 1-Phenyl-3-methyl-4-acyl-5- pyrazolones. N-(3-phenyl-n-propyl)-1-phenyl-2-aminopropane were prepared by acylation of the appropriate amine with 3-phenylpropionyl chloride followed by reduction of the resulting amide with either LiA1H4. For the preparation of the phenylacetyl (PA) and 3-phenylpropionyl (PP) derivatives, the corresponding amino acids were coupled in the usual manner with phenylacetyl chloride or 3-phenylpropionyl chloride in the presence of either NaOH(PA-LD- and DL-Pgly. 3-Phenylpropionyl chloride (4) was treated with diazomethane to give diazoketone. Allyloxy resin 12 was acylated with 3-phenylpropionyl chloride and treated with 50% TFA for 1 h followed by treatment with Pd(PPh3)4/PPh3 in solution to furnish the desired hydrox- amic acid. |
| 备注 | Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, amines, alcohols, active metals, bases, water, moisture. |
| MDL | MFCD00000748 |
| EINECS | 211-443-6 |
| 分子式 | C6H5(CH2)2COCl |
| 分子量 | 168.62 |
| 熔点 | -7° |
| 沸点 | 225° |
| 闪点 | 108°(226°F) |
| 密度 | 1.135 |
| 折射率 | 1.5265 |
| 灵敏度 | Moisture Sensitive. Ambient temperatures. |
| 形态 | Liquid |
| 溶解性 | Soluble in water (reacts), and ether. |
| Beilstein | 742586 |
| 包装组 | II |
| 危险类别 | 20-34 Harmful by inhalation.Causes burns. |
安全信息
| 危险等级 | 8 |
| 安全等级 | 26-36/37/39-45 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). |
| RTECS | MW5652395 |
| 欧盟危险品标志 |   |
| TSCA | 是 |
GHS危害和防范说明
| GHS符号 |   |
| Hazard Statements | H332-H314-H318 Harmful if inhaled.Causes severe skin burns and eye damage.Causes serious eye damage. |
| Precautionary Statements | P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations. |
