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Isopropyldiphenylphosphine
产品编号:3101848
规格:97%
CAS NO:6372-40-3
包装规格:2 G
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
31018482 G896
产品别名

6372-40-3

异丙基联苯膦

Isopropyldiphenylphosphine

NSC 244305

结构式
基本信息
Linear Formula【线性分子式】
(C6H5)2PCH(CH3)2
Molecular weight
228.27
EC number【EC 号】
228-902-1
MDL number
MFCD00015028
PubChem Substance ID【PubChem化学物质编号】
24860440
NACRES
NA.22
Application【应用】
Catalyst in:
  • Nickel/Lewis acid-catalyzed aryl- and alkenylcyanation of unsaturated bonds
  • Nickel/Lewis Acid-Catalyzed Cyanoesterification and Cyanocarbamoylation of Alkynes
  • Methoxycarbonylation reactions (palladium complex)
  • Decarboxylative cross-coupling in the presence of palladium
  • Asymmetric hydrogenation of quinolines catalyzed by iridium complexes of BINOL-derived diphosphonites
  • Hydroesterification of vinylarenes in complex with palladium

  • Ligand precatalyst for room-temperature Heck coupling reactions
产品性质
Quality Level【质量水平】
200
Assay【测定】
97%
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
bp
165 ℃/11 mmHg (lit.)
mp
40-43 ℃ (lit.)
functional group【官能团】
phosphine
SMILES string
CC(C)P(c1ccccc1)c2ccccc2
InChI
1S/C15H17P/c1-13(2)16(14-9-5-3-6-10-14)15-11-7-4-8-12-15/h3-13H,1-2H3
InChI key
LLZAIAIZAVMQIG-UHFFFAOYSA-N
packaging【包装】
2 g in glass bottle
安全信息
Pictograms【象形图】
GHS07
Signal word【警示用语:】
Warning
Hazard Statements
H315 - H319 - H335
Precautionary Statements
P302 + P352 - P305 + P351 + P338
Hazard Classifications【危险分类】
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs【靶器官】
Respiratory system
Storage Class Code【储存分类代码】
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)【闪点(F)】
235.4 °F - closed cup
Flash Point(C)【闪点(C)】
113 ℃ - closed cup
Personal Protective Equipment【个人防护装备】
dust mask type N95 (US), Eyeshields, Gloves
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