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1-苯基-1-三甲基硅氧乙烯

1-Phenyl-1-trimethylsiloxyethylene
产品编号:3113414
规格:98%
CAS NO:13735-81-4
包装规格:5 G,25 G
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
31134145 G1047
311341425 G4110
产品别名

13735-81-4

1-苯基-1-三甲基硅氧乙烯

1-Phenyl-1-trimethylsiloxyethylene

α-(Trimethylsiloxy)styrene

Acetophenone enol trimethylsilyl ether

1-苯基-1-三甲硅氧基乙烯

α-(三甲基硅氧基)苯乙烯

结构式
基本信息
Linear Formula【线性分子式】
C6H5C(=CH2)OSi(CH3)3
Molecular weight
192.33
Beilstein
1306914
EC number【EC 号】
237-308-1
MDL number
MFCD00008582
PubChem Substance ID【PubChem化学物质编号】
24854075
NACRES
NA.22
General description【一般描述】
1-Phenyl-1-trimethylsiloxyethylene is a styrene type silyl enol ether, reacts with formaldehyde and 2,4-pentanedione to yield the corresponding dihydropyran. It also undergoes Mukaiyama aldol reaction with aldehydes in water in the presence of amphiphilic calix[6]arene derivatives as surfactants.
Application【应用】
1-Phenyl-1-trimethylsiloxyethylene has been used in the synthesis of:
  • β-amino ketones in water via Mannich-type reaction
  • cis-2,6-disubstituted dihydropyrans via three-component, one-pot cascade reaction
产品性质
Quality Level【质量水平】
100
vapor density【蒸汽密度】
>1 (vs air)
Assay【测定】
98%
form【形式】
liquid
refractive index【折射率】
n20/D 1.502 (lit.)
bp
88-89 ℃/11 mmHg (lit.)
density
0.938 g/mL at 25 ℃ (lit.)
storage temp.【储存温度】
2-8℃
SMILES string
C[Si](C)(C)OC(=C)c1ccccc1
InChI
1S/C11H16OSi/c1-10(12-13(2,3)4)11-8-6-5-7-9-11/h5-9H,1H2,2-4H3
InChI key
AFFPCIMDERUIST-UHFFFAOYSA-N
packaging【包装】
5, 25 g in glass bottle
安全信息
Pictograms【象形图】
GHS07
Signal word【警示用语:】
Warning
Hazard Statements
H315 - H319 - H335
Precautionary Statements
P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
Hazard Classifications【危险分类】
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs【靶器官】
Respiratory system
Storage Class Code【储存分类代码】
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)【闪点(F)】
168.8 °F - closed cup
Flash Point(C)【闪点(C)】
76 ℃ - closed cup
Personal Protective Equipment【个人防护装备】
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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