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1-苯基-1-三甲基硅氧乙烯
1-Phenyl-1-trimethylsiloxyethylene
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产品编号 | 包装单位 | 单价(元) | 国内现货 | 国外库存 | 询价单 |
3113414 | 5 G | 1047 | |||
3113414 | 25 G | 4110 |
产品别名
13735-81-4
1-苯基-1-三甲基硅氧乙烯
1-Phenyl-1-trimethylsiloxyethylene
α-(Trimethylsiloxy)styrene
Acetophenone enol trimethylsilyl ether
1-苯基-1-三甲硅氧基乙烯
α-(三甲基硅氧基)苯乙烯
结构式
基本信息
Linear Formula【线性分子式】 | C6H5C(=CH2)OSi(CH3)3 |
Molecular weight | 192.33 |
Beilstein | 1306914 |
EC number【EC 号】 | 237-308-1 |
MDL number | MFCD00008582 |
PubChem Substance ID【PubChem化学物质编号】 | 24854075 |
NACRES | NA.22 |
General description【一般描述】 | 1-Phenyl-1-trimethylsiloxyethylene is a styrene type silyl enol ether, reacts with formaldehyde and 2,4-pentanedione to yield the corresponding dihydropyran. It also undergoes Mukaiyama aldol reaction with aldehydes in water in the presence of amphiphilic calix[6]arene derivatives as surfactants. |
Application【应用】 | 1-Phenyl-1-trimethylsiloxyethylene has been used in the synthesis of:
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产品性质
Quality Level【质量水平】 | 100 |
vapor density【蒸汽密度】 | >1 (vs air) |
Assay【测定】 | 98% |
form【形式】 | liquid |
refractive index【折射率】 | n |
bp | 88-89 ℃/11 mmHg (lit.) |
density | 0.938 g/mL at 25 ℃ (lit.) |
storage temp.【储存温度】 | 2-8℃ |
SMILES string | C[Si](C)(C)OC(=C)c1ccccc1 |
InChI | 1S/C11H16OSi/c1-10(12-13(2,3)4)11-8-6-5-7-9-11/h5-9H,1H2,2-4H3 |
InChI key | AFFPCIMDERUIST-UHFFFAOYSA-N |
packaging【包装】 | 5, 25 g in glass bottle |
安全信息
Pictograms【象形图】 | GHS07 |
Signal word【警示用语:】 | Warning |
Hazard Statements | H315 - H319 - H335 |
Precautionary Statements | P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338 |
Hazard Classifications【危险分类】 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
Target Organs【靶器官】 | Respiratory system |
Storage Class Code【储存分类代码】 | 10 - Combustible liquids |
WGK | WGK 3 |
Flash Point(F)【闪点(F)】 | 168.8 °F - closed cup |
Flash Point(C)【闪点(C)】 | 76 ℃ - closed cup |
Personal Protective Equipment【个人防护装备】 | Eyeshields, Gloves, type ABEK (EN14387) respirator filter |