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SnAP 2,3-Bicyclo-(3,4-Pyr)M试剂
SnAP 2,3-Bicyclo-(3,4-Pyr) M Reagent
产品别名
SnAP 2,3-Bicyclo-(3,4-Pyr)M试剂
SnAP 2,3-Bicyclo-(3,4-Pyr) M Reagent
(3R,4R)-tert-butyl 3-amino-4-((tributylstannyl)methoxy) pyrrolidine-1-carboxylate
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C22H46N2O3Sn |
| Molecular weight | 505.32 |
| PubChem Substance ID【PubChem化学物质编号】 | 329768847 |
| NACRES | NA.22 |
| Application【应用】 | SnAP Reagents provide a one-step route, in tandem with various aldehyde substrates, to saturated N-heterocycles. The synthesis of N-heterocycles through SnAP Reagents requires mild reaction conditions, and aldehydes bearing aryl, heteroaryl, glyoxyl, aliphatic, and halogenated groups are well tolerated. This product was introduced in collaboration with the Bode Research Group |
| Other Notes【其他说明】 | Technology spotlight: SnAP Reagents Professor product portal: Jeffrey Bode Research Group SnAP Reagents for the Synthesis of Piperazines and Morpholines SnAP reagents for the one-step synthesis of medium-ring saturated N-heterocycles from aldehydes SnAP Reagents for a Cross-Coupling Approach to the One-Step Synthesis of Saturated N-Heterocycles Bespoke SnAP Reagents for the Synthesis of C-Substituted Spirocyclic and Bicyclic Saturated N-Heterocycles |
产品性质
| form【形式】 | liquid |
| Quality Level【质量水平】 | 100 |
| density | 1.180 at 25 ℃ |
| storage temp.【储存温度】 | −20℃ |
| SMILES string | CCCC[Sn](CCCC)(CO[C@H]1CN(C(OC(C)(C)C)=O)C[C@@H]1N)CCCC |
| InChI | 1S/C10H19N2O3.3C4H9.Sn/c1-10(2,3)15-9(13)12-5-7(11)8(6-12)14-4;3*1-3-4-2;/h7-8H,4-6,11H2,1-3H3;3*1,3-4H2,2H3;/t7-,8-;;;;/m0..../s1 |
| InChI key | URTKNAYUDTUPJM-CFACWHMASA-N |
| packaging【包装】 | 500 mg in glass bottle |
安全信息
| Pictograms【象形图】 | GHS06,GHS08,GHS09 |
| Signal word【警示用语：】 | Danger |
| Hazard Statements | H301 - H312 - H315 - H319 - H360FD - H372 - H410 |
| Precautionary Statements | P202 - P273 - P280 - P301 + P310 - P302 + P352 + P312 - P305 + P351 + P338 |
| Hazard Classifications【危险分类】 | Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 1 |
| Storage Class Code【储存分类代码】 | 6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects |
| WGK | WGK 3 |
