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2-烯丙基环己酮

2-Allylcyclohexanone
产品编号:3270611
规格:97%
CAS NO:94-66-6
包装规格:5 G
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
32706115 G2260
产品别名

94-66-6

2-烯丙基环己酮

2-Allylcyclohexanone

结构式
基本信息
Linear Formula【线性分子式】
H2C=CHCH2C6H9(=O)
Molecular weight
138.21
EC number【EC 号】
202-352-2
MDL number
MFCD00043548
PubChem Substance ID【PubChem化学物质编号】
24865329
NACRES
NA.22
General description【一般描述】
2-Allylcyclohexanone is a β,γ-unsaturated ketone. Selective oxidation of 2-allylcyclohexanone by benzonitrile-hydrogen peroxide has been reported. Asymmetric synthesis of 2-alkylcyclohexanones by alkylation of cyclohexanone enamines (III) of L-proline ester derivatives has been described. Oxidation of 2-allylcyclohexanone by 90% hydrogen peroxide catalyzed by arsonated polystyrene has been studied.
Application【应用】
2-Allylcyclohexanone may be used in the synthesis of the following:
  • bicyclo[3.3.1]non-2-en-9-one
  • R-(-)-epilachnene, an antipode of the defensive droplets from the Mexican bean beetle, Epilachna varivestis
产品性质
Quality Level【质量水平】
100
Assay【测定】
97%
refractive index【折射率】
n20/D 1.469 (lit.)
bp
94 ℃/23 mmHg (lit.)
density
0.927 g/mL at 25 ℃ (lit.)
SMILES string
C=CCC1CCCCC1=O
InChI
1S/C9H14O/c1-2-5-8-6-3-4-7-9(8)10/h2,8H,1,3-7H2
InChI key
UPGHEUSRLZSXAE-UHFFFAOYSA-N
packaging【包装】
1, 5 g in glass bottle
安全信息
Pictograms【象形图】
GHS07
Signal word【警示用语:】
Warning
Hazard Statements
H302 + H312 + H332 - H315 - H319 - H335
Precautionary Statements
P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
Hazard Classifications【危险分类】
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs【靶器官】
Respiratory system
Storage Class Code【储存分类代码】
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)【闪点(F)】
235.4 °F - closed cup
Flash Point(C)【闪点(C)】
113 ℃ - closed cup
Personal Protective Equipment【个人防护装备】
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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