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2-氯-4,4,5,5-四甲基-1,3,2-二氧磷杂环戊烷
2-Chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane
产品别名
14812-59-0
2-氯-4,4,5,5-四甲基-1,3,2-二氧磷杂环戊烷
2-Chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C6H12ClO2P |
| Molecular weight | 182.59 |
| MDL number | MFCD00274239 |
| PubChem Substance ID【PubChem化学物质编号】 | 24868346 |
| NACRES | NA.22 |
| Application【应用】 | 2-氯-4,4,5,5-四甲基-1,3,2-二氧磷杂环戊烷(TMDP)可用于：
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产品性质
| Assay【测定】 | 95% |
| reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: ligand |
| refractive index【折射率】 | n |
| bp | 81.5-82 ℃/13 mmHg (lit.) |
| density | 1.149 g/mL at 25 ℃ (lit.) |
| functional group【官能团】 | phosphine |
| SMILES string | CC1(C)OP(Cl)OC1(C)C |
| InChI | 1S/C6H12ClO2P/c1-5(2)6(3,4)9-10(7)8-5/h1-4H3 |
| InChI key | WGPCXYWWBFBNSS-UHFFFAOYSA-N |
| packaging【包装】 | 1, 5 g in glass bottle |
安全信息
| Pictograms【象形图】 | GHS05 |
| Signal word【警示用语：】 | Danger |
| Hazard Statements | H314 |
| Precautionary Statements | P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 |
| Hazard Classifications【危险分类】 | Eye Dam. 1 - Skin Corr. 1B |
| Supp Hazards【补充剂危害】 | EUH014 |
| Storage Class Code【储存分类代码】 | 8A - Combustible, corrosive hazardous materials |
| WGK | WGK 3 |
| Flash Point(F)【闪点(F)】 | 235.4 °F - closed cup |
| Flash Point(C)【闪点(C)】 | 113 ℃ - closed cup |
| Personal Protective Equipment【个人防护装备】 | Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter |
