您的位置：首页 > 产品中心 > 2-cyanophenyl sulfofluoridate
2-cyanophenyl sulfofluoridate
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C7H4FNO3S |
| Molecular weight | 201.17 |
| PubChem Substance ID【PubChem化学物质编号】 | 329772673 |
| General description【一般描述】 | 2-Cyanophenyl sulfofluoridate is an aryl fluorosulfate. It undergoes Suzuki-Miyaura reaction with aryl boronic acid in the presence of Pd(OAc)2 and Et3N to afford the corresponding biaryl derivative. 2-Cyanophenyl sulfofluoridate can be synthesized from the reaction between phenol and sulfuryl fluoride in the presence of triethylamine. |
| Application【应用】 | The following aryl fluorosulfate can be utilized as a cross-coupling partner in Suzuki-Miyaura reactions. The standard reaction conditions for these palladium-catalyzed C-C bond formations are ligand-free and can be performed in water, at room temperatre and are not air sensitive. |
| Other Notes【其他说明】 | Palladium-Catalyzed, Ligand-Free Suzuki Reaction in Water Using Aryl Fluorosulfates |
产品性质
| Quality Level【质量水平】 | 100 |
| SMILES string | O=S(F)(OC1=CC=CC=C1C#N)=O |
| InChI | 1S/C7H4FNO3S/c8-13(10,11)12-7-4-2-1-3-6(7)5-9/h1-4H |
| InChI key | FWHISILUCPTNBH-UHFFFAOYSA-N |
| packaging【包装】 | 500 mg in glass bottle |
安全信息
| Pictograms【象形图】 | GHS07 |
| Signal word【警示用语：】 | Warning |
| Hazard Statements | H315 - H319 - H335 |
| Precautionary Statements | P280 - P304 + P340 + P312 - P305 + P351 + P338 - P337 + P313 |
| Hazard Classifications【危险分类】 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
| Target Organs【靶器官】 | Respiratory system |
| Storage Class Code【储存分类代码】 | 12 - Non Combustible Liquids |
| WGK | WGK 3 |
