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4-乙酰氨-2,2,6,6-四甲基哌啶-1-氧

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl
产品编号:3309157
规格:purum, ≥98.0% (HPLC)
CAS NO:14691-89-5
包装规格:1G,5G
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
33091571G607
33091575G2760
产品别名

14691-89-5

4-乙酰氨-2,2,6,6-四甲基哌啶-1-氧

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C11H21N2O2
Molecular weight
213.30
Beilstein
3546225
EC number【EC 号】
423-840-3
MDL number
MFCD00043593
PubChem Substance ID【PubChem化学物质编号】
329747053
NACRES
NA.22
General description【一般描述】
4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl undergoes one-electron oxidation and reduction reactions. Reaction products were analyzed by 1H, 13C and 15N NMR spectral data.
Application【应用】
4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl radical may be employed in the catalytic system used for the regioselective oxidation of curdlan. It may be employed as model nitroxyl radical to study its reaction with thiophosgene. Reaction afforded 2,2,6,6-tetramethylpiperidine and 2,2,6,6-tetramethyl-1-hydroxypiperidine as major products.
Other Notes【其他说明】
将醇轻度氧化成羰基的新型氧化剂
产品性质
Quality Level【质量水平】
200
grade【等级】
purum
Assay【测定】
≥98.0% (HPLC)
greener alternative product score【环保替代产品得分】
old score: 9
new score: 8
Find out more about DOZN™ Scoring
greener alternative product characteristics【环保替代产品特性】
Waste Prevention
Safer Solvents and Auxiliaries
Inherently Safer Chemistry for Accident Prevention
Learn more about the Principles of Green Chemistry.
mp
143-145 ℃ (lit.)
143-146 ℃
greener alternative category【环保替代产品分类】
Re-engineered
storage temp.【储存温度】
2-8℃
SMILES string
CC(=O)NC1CC(C)(C)N([O])C(C)(C)C1
InChI
1S/C11H21N2O2/c1-8(14)12-9-6-10(2,3)13(15)11(4,5)7-9/h9H,6-7H2,1-5H3,(H,12,14)
InChI key
UXBLSWOMIHTQPH-UHFFFAOYSA-N
安全信息
Pictograms【象形图】
GHS07
Signal word【警示用语:】
Warning
Hazard Statements
H302
Precautionary Statements
P264 - P270 - P301 + P312 + P330 - P501
Hazard Classifications【危险分类】
Acute Tox. 4 Oral
Storage Class Code【储存分类代码】
13 - Non Combustible Solids
WGK
WGK 1
Personal Protective Equipment【个人防护装备】
dust mask type N95 (US), Eyeshields, Gloves
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