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(dppf)Ni(o-tolyl)Cl
产品价格查看更多规格...
| 产品编号 | 包装单位 | 单价(元) | 国内现货 | 国外库存 | 询价单 |
| 3317601 | 250 MG | 830 | |||
| 3317601 | 1 G | 2560 |
产品别名
1501945-23-8
(dppf)Ni(o-tolyl)Cl
Buchwald Ni Catalyst
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C41H35ClFeNiP2 |
| Molecular weight | 739.66 |
| MDL number | MFCD28411349 |
| PubChem Substance ID【PubChem化学物质编号】 | 329768766 |
| General description【一般描述】 | (dppf)Ni(o-tolyl)Cl is an air stable reagent. Its crystal structure has been investigated by X-ray studies. (dppf)Ni(o-tolyl)Cl can be prepared from (Ph3P)2Ni(o-tolyl)Cl. It is widely employed as a precatalyst for various C-N bond formation reactions. Efficacy of (dppf)Ni(o-tolyl)Cl as a precatalyst for the amination of 4-n-butylchlorobenzene with morpholine under various optimized reaction conditions has been investigated. |
产品性质
| Assay【测定】 | 95% |
| Quality Level【质量水平】 | 100 |
| form【形式】 | powder |
| reaction suitability | core: nickel reagent type: catalyst |
| mp | 173 ℃ |
| storage temp.【储存温度】 | 2-8℃ |
| SMILES string | CC1=CC=CC=C1[Ni]Cl.[C]2(P(C3=CC=CC=C3)C4=CC=CC=C4)[C][C][C][C]2.[C]5(P(C6=CC=CC=C6)C7=CC=CC=C7)[C][C][C][C]5.[Fe] |
| InChI | 1S/2C17H14P.C7H7.ClH.Fe.Ni/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;1-7-5-3-2-4-6-7;;;/h2*1-14H;2-5H,1H3;1H;;/q;;;;;+1/p-1 |
| InChI key | LGLPATFHWYLMCO-UHFFFAOYSA-M |
| packaging【包装】 | 1 g in glass bottle 250 mg in glass bottle |
安全信息
| Pictograms【象形图】 | GHS08,GHS09 |
| Signal word【警示用语：】 | Danger |
| Hazard Statements | H317 - H334 - H341 - H350 - H360 - H372 - H410 |
| Precautionary Statements | P201 - P273 - P280 - P302 + P352 - P308 + P313 |
| Hazard Classifications【危险分类】 | Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 1 Inhalation |
| Storage Class Code【储存分类代码】 | 6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects |
| WGK | WGK 3 |
