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(R)-(4,4′,6,6′-Tetramethoxybiphenyl-2,2′-diyl)bis(bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine

产品编号:3324744
规格:97%
CAS NO:1365531-98-1
包装规格:100 MG,500 MG
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
3324744100 MG1210
3324744500 MG4390
产品别名

1365531-98-1

(R)-(4,4′,6,6′-Tetramethoxybiphenyl-2,2′-diyl)bis(bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine

(R)-DTBM-Garphos

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C76H108O8P2
Molecular weight
1211.61
MDL number
MFCD22666441
PubChem Substance ID【PubChem化学物质编号】
329766935
NACRES
NA.22
Application【应用】
Versatile chiral diphosphine ligand.
Legal Information【法律信息】
Sold under license from Kanata Chemical Technologies Inc. for research purposes only.
Garphos is a trademark of Kanata Chemical Technologies, Inc.
产品性质
Assay【测定】
97%
optical activity【旋光性】
[α]22/D +18.0°, c = 0.5% in chloroform
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
functional group【官能团】
phosphine
SMILES string
COc1cc(OC)c(c(c1)P(c2cc(c(OC)c(c2)C(C)(C)C)C(C)(C)C)c3cc(c(OC)c(c3)C(C)(C)C)C(C)(C)C)-c4c(OC)cc(OC)cc4P(c5cc(c(OC)c(c5)C(C)(C)C)C(C)(C)C)c6cc(c(OC)c(c6)C(C)(C)C)C(C)(C)C
InChI
1S/C76H108O8P2/c1-69(2,3)51-37-47(38-52(65(51)81-29)70(4,5)6)85(48-39-53(71(7,8)9)66(82-30)54(40-48)72(10,11)12)61-35-45(77-25)33-59(79-27)63(61)64-60(80-28)34-46(78-26)36-62(64)86(49-41-55(73(13,14)15)67(83-31)56(42-49)74(16,17)18)50-43-57(75(19,20)21)68(84-32)58(44-50)76(22,23)24/h33-44H,1-32H3
InChI key
KACYLFSRRUJDSY-UHFFFAOYSA-N
packaging【包装】
100, 500 mg in glass bottle
安全信息
Storage Class Code【储存分类代码】
11 - Combustible Solids
WGK
WGK 3
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