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(R)-α,α-双[3,5-双(三氟甲基)苯基]-2-吡咯烷甲醇三甲基硅基醚

(R)-α,α-Bis[3,5-bis(trifluoromethyl)phenyl]-2-pyrrolidinemethanol trimethylsilyl ether
产品编号:3327459
规格:technical grade
CAS NO:908303-26-4
包装规格:1 G,5 G
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
33274591 G2010
33274595 G6120
产品别名

908303-26-4

(R)-α,α-双[3,5-双(三氟甲基)苯基]-2-吡咯烷甲醇三甲基硅基醚

(R)-α,α-Bis[3,5-bis(trifluoromethyl)phenyl]-2-pyrrolidinemethanol trimethylsilyl ether

(R)-2-[(Bis(3,5-bis(trifluoromethyl)phenyl)]trimethylsilanyloxy)methyl]pyrrolidine

(R)-α,α-Bis[3,5-bis(trifluoromethyl)phenyl]prolinol trimethylsilyl ether

(R)-2-[(Bis(3,5-bis(trifluoromethyl)phenyl)]trimethylsilyloxy)methyl]pyrrolidine

(R)-2-[(双(3,5-双(三氟甲基)苯基)]三甲基甲硅氧基)甲基]吡咯烷

(R)-2-[(双(3,5-双(三氟甲基)苯基)]三甲基硅烷氧基)甲基]吡咯烷

(R)-α,α-双[3,5-双(三氟甲基)苯基]脯氨醇三甲基硅醚

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C24H23F12NOSi
Molecular weight
597.51
MDL number
MFCD09750448
PubChem Substance ID【PubChem化学物质编号】
24885357
NACRES
NA.22
Application【应用】
Catalyst involved in:
  • Cyclocondensation of enals with methylenepyrrolidines
  • Organocatalytic additions of β-ketosulfoxides to conjugated aldehydes
  • Organocatalytic aza-Michael reactions
  • Stereoselective propargylic alkylation of propargylic esters with aldehydes
  • Epoxidation or aziridination of α,β-unsaturated aldehydes and Feist-Benary reactions of 1,3-dicarbonyls
产品性质
grade【等级】
technical grade
optical purity【光学纯度】
enantiomeric excess: ≥99.0% (HPLC)
mp
46-55 ℃
SMILES string
C[Si](C)(C)OC([C@H]1CCCN1)(c2cc(cc(c2)C(F)(F)F)C(F)(F)F)c3cc(cc(c3)C(F)(F)F)C(F)(F)F
InChI
1S/C24H23F12NOSi/c1-39(2,3)38-20(19-5-4-6-37-19,13-7-15(21(25,26)27)11-16(8-13)22(28,29)30)14-9-17(23(31,32)33)12-18(10-14)24(34,35)36/h7-12,19,37H,4-6H2,1-3H3/t19-/m1/s1
InChI key
MOHRGTBNEJKFMB-LJQANCHMSA-N
packaging【包装】
1, 5 g in glass bottle
安全信息
Pictograms【象形图】
GHS07
Signal word【警示用语:】
Warning
Hazard Statements
H315 - H319 - H335
Precautionary Statements
P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
Hazard Classifications【危险分类】
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs【靶器官】
Respiratory system
Storage Class Code【储存分类代码】
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)【闪点(F)】
230.0 °F - closed cup
Flash Point(C)【闪点(C)】
> 110 ℃ - closed cup
Personal Protective Equipment【个人防护装备】
dust mask type N95 (US), Eyeshields, Gloves
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