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8-氨基-5-甲氧基喹啉
8-Amino-5-methoxyquinoline
产品价格查看更多规格...
| 产品编号 | 包装单位 | 单价(元) | 国内现货 | 国外库存 | 询价单 |
| 3333951 | 1 G | 1095 |
产品别名
30465-68-0
8-氨基-5-甲氧基喹啉
8-Amino-5-methoxyquinoline
5-Methoxy-8-quinolinamine
MQ
Gong Chen Auxiliary
Chen Auxilliary
MQ Auxiliary
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C10H10N2O |
| Molecular weight | 174.20 |
| MDL number | MFCD01593679 |
| PubChem Substance ID【PubChem化学物质编号】 | 329768733 |
| General description【一般描述】 | 8-Amino-5-methoxyquinoline is a substituted quinoline derivative that can be prepared using 5-chloro-2-nitroaniline as a starting material. It can act as an easily removable directing group and also mediate C-H activation. These properties have been useful for synthesizing isomeric dibenzoxazepinones and complex pyrrolidinones from compounds containing 8-amino-5-methoxyquinoline moiety. |
| Application【应用】 | The Chen auxiliary was reported to be an effective directing group in the synthesis of pyrrolidones from assisting in the activation of C(sp3)-H bonds and can be readily installed through amide bond formation and removed through mild conditions using CAN at room temperature. |
| Other Notes【其他说明】 | Use of a Readily Removable Auxiliary Group for the Synthesis of Pyrrolidones by the Palladium-Catalyzed Intramolecular Amination of Unactivated γ C(sp3)-H bonds |
产品性质
| Quality Level【质量水平】 | 100 |
| Assay【测定】 | 95% |
| form【形式】 | powder |
| mp | 90-95 ℃ |
| SMILES string | NC1=CC=C(OC)C2=CC=CN=C21 |
| InChI | 1S/C10H10N2O/c1-13-9-5-4-8(11)10-7(9)3-2-6-12-10/h2-6H,11H2,1H3 |
| InChI key | MFLLTRMMFHENCM-UHFFFAOYSA-N |
| packaging【包装】 | 1 g in glass bottle |
安全信息
| Pictograms【象形图】 | GHS07 |
| Signal word【警示用语：】 | Warning |
| Hazard Statements | H315 - H319 - H335 |
| Precautionary Statements | P302 + P352 - P305 + P351 + P338 |
| Hazard Classifications【危险分类】 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
| Target Organs【靶器官】 | Respiratory system |
| Storage Class Code【储存分类代码】 | 11 - Combustible Solids |
| WGK | WGK 3 |
