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(S,R,R)-Elenor Amination Reagent
产品别名
139331-02-5
(S,R,R)-Elenor Amination Reagent
3H-3a,6-Methano-2,1-benzisothiazole-1(4H)-carboxamide, tetrahydro-N-hydroxy-8,8-dimethyl-, 2,2-dioxide, (3aS,6R,7aR)-
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C11H18N2O4S |
| Molecular weight | 274.34 |
| PubChem Substance ID【PubChem化学物质编号】 | 329769052 |
| NACRES | NA.22 |
| Application【应用】 | The following hydroxyamide is a chiral electrophilic nitroso reagent for the transfer of nitrogen to enol ethers. This methology was reported by the Read de Alaniz Group, is a mild approach that can be performed at room temperature and in the presence of air. |
| Other Notes【其他说明】 | Asymmetric Electrophilic α-Amination of Silyl Enol Ether Derivatives via the Nitrosocarbonyl Hetero-ene Reaction |
产品性质
| form【形式】 | powder |
| Quality Level【质量水平】 | 100 |
| storage temp.【储存温度】 | 2-8℃ |
| SMILES string | O=C(N1S(C[C@]2(C3(C)C)CC[C@]3([H])C[C@@]12[H])(=O)=O)NO |
| InChI | 1S/C11H18N2O4S/c1-10(2)7-3-4-11(10)6-18(16,17)13(8(11)5-7)9(14)12-15/h7-8,15H,3-6H2,1-2H3,(H,12,14)/t7-,8-,11-/m1/s1 |
| InChI key | FYSORZDAOUCPGD-SOCHQFKDSA-N |
| packaging【包装】 | 1 g in glass bottle |
安全信息
| Pictograms【象形图】 | GHS07 |
| Signal word【警示用语：】 | Warning |
| Hazard Statements | H315 - H319 - H335 |
| Precautionary Statements | P302 + P352 - P305 + P351 + P338 |
| Hazard Classifications【危险分类】 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
| Target Organs【靶器官】 | Respiratory system |
| Storage Class Code【储存分类代码】 | 11 - Combustible Solids |
| WGK | WGK 3 |
