( S,S )-(+)- N,N′-双(3,5-二- 叔 -丁基水杨醛)-1,2-环己烷二氨基锰 (III) 氯化物

[[[(CH₃)₃C]₂C₆H₂-2-(O-)CH=N]₂C₆H₁₀]MnCl

635.20

MFCD02101663

24865247

NA.22

(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride is a metal-salen complex that can catalyze a variety of asymmetric transformations.

Reactant involved in:

• Studies of intercalative binding with ct-DNA and radical scavenging antioxidant activity
• Immobilization on phenoxy-modified zirconium poly(styrenephenylvinylphosphonate)
• Synthesis of derivatvies for studies of conformational models of enantioselective reactions

Catalyst involved in:

• Asymmetric epoxidation of olefins
• Immobilization on ionic liquid modified mesoporous silica for oxidative kinetic resolution of racemic secondary alcohols†
• Immobilization on diamine modified zirconium olig-styrenyl phosphonate hydrogen phosphate for epoxidation of styrene

非官能化烯烃类的 Salen (Mn)-催化不对称环氧化反应。获得各种底物(特别是顺式-烯烃)的高对映立体选择性和产量。一些用途包括合成紫杉醇侧链和顺式-1-氨基-2-茚醇。Jacobsen 催化剂还用于硅烯醇醚的不对称 α-羟基化。用于各种烯烃不对称环氧化反应的催化剂。

经 Shasun Chemicals and Drugs Limited 授权，使用 Jacobsen HKR 技术制造。

200

330-332 ℃ (lit.)

CC(C)(C)c1cc2C=[N@@H]3[C@H]4CCCC[C@@H]4[N@H]5=Cc6cc(cc(c6O[Mn]35(Cl)Oc2c(c1)C(C)(C)C)C(C)(C)C)C(C)(C)C

1S/C36H54N2O2.ClH.Mn/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;/h17-22,29-30,39-40H,13-16H2,1-12H3;1H;/q;;+3/p-3/b37-21+,38-22+;;/t29-,30-;;/m0../s1

LJVAWOSDJSQANR-RUIQGICGSA-K

1, 5, 25 g in glass bottle

GHS07

Warning

H315 - H319 - H335

P302 + P352 - P305 + P351 + P338

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Respiratory system

11 - Combustible Solids

WGK 3

dust mask type N95 (US), Eyeshields, Gloves