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1,1′-双(苯基亚膦基)二茂铁

1,1′-Bis(phenylphosphinidene)ferrocene
产品编号:3345269
规格:97%
CAS NO:72954-06-4
包装规格:1 G
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品价格
产品编号包装单位单价(元)国内现货国外库存询价单
33452691 G1390
产品别名

72954-06-4

1,1′-双(苯基亚膦基)二茂铁

1,1′-Bis(phenylphosphinidene)ferrocene

1,1′-(Ferrocenediyl)phenylphosphine

1,1′-(二茂铁二基)苯膦

结构式
基本信息
Linear Formula【线性分子式】
C5H4PC6H5C5H4Fe
Molecular weight
292.09
MDL number
MFCD04974069
PubChem Substance ID【PubChem化学物质编号】
24880349
NACRES
NA.22
Application【应用】
Reactant for:
  • Preparation of macrocyclic tridentate ferrocenylphosphine ligands
  • Preparation of phosphorus-bridged ferrocenophane with syn and anti conformations
  • Reaction with phenyllithium and chlorophosphine to give ferrocenediyl ligand and its rhodium complex catalyst for selective hydroformylation of alkenes
  • Ring-opening reactions via ring slippage
  • Preparation of palladium chloro (ferrocene-bridged)phosphine-phosphonite complex for catalysis of Heck reaction of iodobenzene with Me acrylate
产品性质
Quality Level【质量水平】
100
Assay【测定】
97%
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
mp
88-92 ℃ (lit.)
functional group【官能团】
phosphine
storage temp.【储存温度】
2-8℃
SMILES string
[Fe].[CH]1[CH][CH][C]([CH]1)P([C]2[CH][CH][CH][CH]2)c3ccccc3
InChI
1S/C16H13P.Fe/c1-2-8-14(9-3-1)17(15-10-4-5-11-15)16-12-6-7-13-16;/h1-13H;
InChI key
HKOUDNXXOXEYNZ-UHFFFAOYSA-N
packaging【包装】
1 g in glass bottle
安全信息
Storage Class Code【储存分类代码】
13 - Non Combustible Solids
WGK
WGK 3
Personal Protective Equipment【个人防护装备】
Eyeshields, Gloves, type N95 (US)
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