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1,3-双(2,4,6-三甲基苯基咪唑-2-亚基(1,4-萘醌)钯(0)二聚体
CX12
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| 产品编号 | 包装单位 | 单价(元) | 国内现货 | 国外库存 | 询价单 |
| 3380651 | 1 G | 2140 |
产品别名
467220-49-1
1,3-双(2,4,6-三甲基苯基咪唑-2-亚基(1,4-萘醌)钯(0)二聚体
CX12
Bis[1,3-dihydro-1,3-(2,4,6-trimethylphenyl)-2H-imidazol-2-ylidene]bis[μ-[(2,3-η)-1,4-naphthalenedione-κO]]di-palladium
1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (1,4-naphthoquinone)palladium(0) dimer
Naphthoquinone-1,3-bis(2,4,6-trimethylphenyl)-imidazole-2-ylidenepalladium(0)
Pd(0)-naphthochinone-1,3-Bis(2,4,6-tri-methylphenyl)imidazol-2-ylidene
双[1,3-二氢-1,3-(2,4,6-三甲基苯基)-2H-咪唑-2-亚基]双[μ-[(2,3-η)-1,4-萘二酮-κO]]二钯，CX 12
钯(0)-萘醌-1,3-双(2,4,6-三甲基苯基)咪唑-2-亚基，CX 12
萘醌-1,3-双(2,4,6-三甲基苯基)-咪唑-2-亚基钯(0)，CX 12
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C62H60N4O4Pd2 |
| Molecular weight | 1138.00 |
| MDL number | MFCD08705778 |
| PubChem Substance ID【PubChem化学物质编号】 | 24884468 |
| NACRES | NA.22 |
| General description【一般描述】 | 1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (1,4-naphthoquinone)palladium(0) dimer is an N-heterocyclic carbene based palladium catalyst that shows high catalytic activity in C-C coupling reactions. |
| Application【应用】 | It can be used as a catalyst in the Kumada cross-coupling of aryl magnesium reagents with functionalized alkyl chlorides at room temperature to form substituted alkanes. |
| Other Notes【其他说明】 | Product of Umicore Additional information available at www.pmc.umicore.com |
产品性质
| description【描述】 | Umicore |
| Quality Level【质量水平】 | 100 |
| reaction suitability | core: palladium reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: catalyst |
| mp | >300 ℃ |
| SMILES string | O=C1C=CC(=O)c2ccccc12.O=C3C=CC(=O)c4ccccc34.Cc5cc(C)c(N6C=CN(C6=[Pd])c7c(C)cc(C)cc7C)c(C)c5.Cc8cc(C)c(N9C=CN(C9=[Pd])c%10c(C)cc(C)cc%10C)c(C)c8 |
| InChI | 1S/2C21H24N2.2C10H6O2.2Pd/c2*1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;2*11-9-5-6-10(12)8-4-2-1-3-7(8)9;;/h2*7-12H,1-6H3;2*1-6H;; |
| InChI key | ZTBFODSKEBBIJJ-UHFFFAOYSA-N |
| packaging【包装】 | 1 g in glass bottle 250 mg in glass bottle |
安全信息
| Pictograms【象形图】 | GHS07 |
| Signal word【警示用语：】 | Warning |
| Hazard Statements | H315 - H317 - H319 - H335 |
| Precautionary Statements | P280 - P302 + P352 - P305 + P351 + P338 |
| Hazard Classifications【危险分类】 | Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3 |
| Target Organs【靶器官】 | Respiratory system |
| Storage Class Code【储存分类代码】 | 11 - Combustible Solids |
| WGK | WGK 3 |
| Personal Protective Equipment【个人防护装备】 | dust mask type N95 (US), Eyeshields, Faceshields, Gloves |
