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苯甲醛二甲缩醛

Benzaldehyde Dimethyl Acetal
产品编号:3412579
规格:95%
CAS NO:1125-88-8
包装规格:100 ML
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
3412579100 ML582
产品别名

1125-88-8

苯甲醛二甲缩醛

Benzaldehyde Dimethyl Acetal

α,α-Dimethoxytoluene

α,α-二甲氧基甲苯

结构式
基本信息
Linear Formula【线性分子式】
C6H5CH(OCH3)2
Molecular weight
152.19
Beilstein
2044501
EC number【EC 号】
214-413-0
MDL number
MFCD00008491
PubChem Substance ID【PubChem化学物质编号】
24863815
NACRES
NA.22
General description【一般描述】
Benzaldehyde dimethyl acetal is an organic building block. Pyridinium tosylate-catalyzed acetal exchange reaction between benzaldehyde dimethyl acetal and 6-O-(tert-butyldiphenylsilyl)-1,2-O-isopropylidene-α-D-glucofuranose is reported to afford 3,5-O-benzylidene-1,2-O-isopropylidene-α-D-glucofuranose. The kinetics of the hydrolysis of benzaldehyde dimethyl acetal over amberlite IR-120 has been studied using a circulated batch reactor in dioxane. One-pot tandem conversion of benzaldehydedimethylacetal to trans-1-nitro-2-phenylethylene has been reported.
Application【应用】
Benzaldehyde dimethyl acetal is suitable for use in the synthesis of 4,6-dihydroxy sugar, required for the total synthesis of Porphyromonas gingivalis 381 derived lipid A. It may be used in the preparation of 1-O-methyl-2,3-di-O-galloyl-β-D-glucose.
产品性质
Quality Level【质量水平】
100
Assay【测定】
95%
refractive index【折射率】
n20/D 1.493 (lit.)
bp
87-89 ℃/18 mmHg (lit.)
density
1.014 g/mL at 25 ℃ (lit.)
SMILES string
COC(OC)c1ccccc1
InChI
1S/C9H12O2/c1-10-9(11-2)8-6-4-3-5-7-8/h3-7,9H,1-2H3
InChI key
HEVMDQBCAHEHDY-UHFFFAOYSA-N
packaging【包装】
100 mL in glass bottle
安全信息
Pictograms【象形图】
GHS07
Signal word【警示用语:】
Warning
Hazard Statements
H302
Precautionary Statements
P301 + P312 + P330
Hazard Classifications【危险分类】
Acute Tox. 4 Oral
Storage Class Code【储存分类代码】
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)【闪点(F)】
156.2 °F - closed cup
Flash Point(C)【闪点(C)】
69 ℃ - closed cup
Personal Protective Equipment【个人防护装备】
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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