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苄氧基丙酮

Benzyloxyacetone
产品编号:3413684
规格:90%
CAS NO:22539-93-1
包装规格:5 G
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
34136845 G3170
产品别名

22539-93-1

苄氧基丙酮

Benzyloxyacetone

1-Benzyloxy-2-propanone

1-苄氧基-2-丙酮

结构式
基本信息
Linear Formula【线性分子式】
C6H5CH2OCH2COCH3
Molecular weight
164.20
MDL number
MFCD01863536
PubChem Substance ID【PubChem化学物质编号】
24872460
NACRES
NA.22
General description【一般描述】
Benzyloxyacetone (α-Benzyloxyacetone) is an α-substituted acetone. It undergoes direct aldol reaction with 4-nitrobenzaldehyde in the presence of (S)-BINAM-L-prolinamide/benzoic acid to form predominantly the syn-diasteroisomer.
Application【应用】
Benzyloxyacetone (1-Benzyloxy-2-propanone) may be used in the synthesis of:
  • 7-benzyloxy-6-methyl-5-hepten-1-yne
  • (Z)-2-methylhept-2-en-6-yn-1-o1
  • (S)-(+)-1,2-propanediol, 1-benzyl ether
It may be used as a starting material in synthesizing (2S,4RS)-4-acetoxy-2-[(benzyloxy)methyl]-2-methyldioxolane and (2R,4RS)-4-acetoxy-2-[(benzyloxy)methyl]-2-methyldioxolane.
产品性质
Assay【测定】
90%
impurities【杂质】
3% (benzyloxy)acetic acid
3% benzyl alcohol
refractive index【折射率】
n20/D 1.512 (lit.)
bp
259 ℃ (lit.)
density
1.04 g/mL at 25 ℃ (lit.)
SMILES string
CC(=O)COCc1ccccc1
InChI
1S/C10H12O2/c1-9(11)7-12-8-10-5-3-2-4-6-10/h2-6H,7-8H2,1H3
InChI key
YHMRKVGUSQWDGZ-UHFFFAOYSA-N
packaging【包装】
5 g in glass bottle
安全信息
Storage Class Code【储存分类代码】
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)【闪点(F)】
230.0 °F - closed cup
Flash Point(C)【闪点(C)】
110 ℃ - closed cup
Personal Protective Equipment【个人防护装备】
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
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