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Bis[(pinacolato)boryl]methane

产品编号:3414513
CAS NO:78782-17-9
包装规格:1 G,5 G
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
34145131 G438
34145135 G1750
产品别名

78782-17-9

Bis[(pinacolato)boryl]methane

2,2′-Methylenebis[4,4,5,5-tetramethyl-1,3,2-dioxaborolane]

Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methane

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C13H26B2O4
Molecular weight
267.97
MDL number
MFCD27977747
PubChem Substance ID【PubChem化学物质编号】
329768437
General description【一般描述】
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
Bis[(pinacolato)boryl]methane is an aryl boronate ester.
Application【应用】
Bis-boronate has been reported by Morken and coworkers to be a key building block in the synthesis of enantioenriched secondary boronate esters, which undergo facile Suzuki-Miyaura coupling with minimal erosion of enantiopurity.
Bis[(pinacolato)boryl]methane may be used in the preparation of trans-vinyl boronate esters, via the Boron-Wittig reaction.
Other Notes【其他说明】
A Catalytic Enantiotopic-Group-Selective Suzuki Reaction for the Construction of Chiral Organoboronates
产品性质
greener alternative product characteristics【环保替代产品特性】
Catalysis
Learn more about the Principles of Green Chemistry.
Quality Level【质量水平】
100
mp
48 ℃
greener alternative category【环保替代产品分类】
Aligned
storage temp.【储存温度】
2-8℃
SMILES string
CC(C(C)(C)O1)(C)OB1CB2OC(C)(C)C(C)(C)O2
InChI
1S/C13H26B2O4/c1-10(2)11(3,4)17-14(16-10)9-15-18-12(5,6)13(7,8)19-15/h9H2,1-8H3
InChI key
MQYZGGWWHUGYDR-UHFFFAOYSA-N
packaging【包装】
1, 5 g in glass bottle
安全信息
Pictograms【象形图】
GHS07
Signal word【警示用语:】
Warning
Hazard Statements
H315 - H319 - H335
Precautionary Statements
P302 + P352 - P305 + P351 + P338
Hazard Classifications【危险分类】
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs【靶器官】
Respiratory system
Storage Class Code【储存分类代码】
11 - Combustible Solids
WGK
WGK 3
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