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双(1,5-环辛二烯)四[双(3,5-三氟甲基)苯基]硼酸铑(I)
Bis(1,5-cyclooctadiene)rhodium(I) tetrakis[bis(3,5-trifluoromethyl)phenyl]borate
产品别名
404573-66-6
双(1,5-环辛二烯)四[双(3,5-三氟甲基)苯基]硼酸铑(I)
Bis(1,5-cyclooctadiene)rhodium(I) tetrakis[bis(3,5-trifluoromethyl)phenyl]borate
结构式
基本信息
Empirical Formula【经验(实验)分子式】 | C48H36BF24Rh |
Molecular weight | 1182.48 |
PubChem Substance ID【PubChem化学物质编号】 | 329761509 |
NACRES | NA.22 |
Application【应用】 | Bis(1,5-cyclooctadiene)rhodium(I) tetrakis[bis(3,5-trifluoromethyl)phenyl]borate can be used as a catalyst for various transformations, including hydrogenation, intramolecular C-H alkenylation, cycloaddition of enynes, and reductive coupling reactions. |
产品性质
reaction suitability | core: rhodium reagent type: catalyst |
Quality Level【质量水平】 | 100 |
mp | 155-156 ℃ (D) |
storage temp.【储存温度】 | −20℃ |
SMILES string | [Rh+].C1CC=CCCC=C1.C2CC=CCCC=C2.FC(F)(F)c3cc(cc(c3)C(F)(F)F)[B-](c4cc(cc(c4)C(F)(F)F)C(F)(F)F)(c5cc(cc(c5)C(F)(F)F)C(F)(F)F)c6cc(cc(c6)C(F)(F)F)C(F)(F)F |
InChI | 1S/C32H12BF24.2C8H12.Rh/c34-25(35,36)13-1-14(26(37,38)39)6-21(5-13)33(22-7-15(27(40,41)42)2-16(8-22)28(43,44)45,23-9-17(29(46,47)48)3-18(10-23)30(49,50)51)24-11-19(31(52,53)54)4-20(12-24)32(55,56)57;2*1-2-4-6-8-7-5-3-1;/h1-12H;2*1-2,7-8H,3-6H2;/q-1;;;+1/b;2*2-1-,8-7-; |
InChI key | HQQAEXNVAYMZON-AUUWQFPRSA-N |
packaging【包装】 | 100, 500 mg in glass bottle |
安全信息
Pictograms【象形图】 | GHS07 |
Signal word【警示用语:】 | Warning |
Hazard Statements | H315 - H319 - H335 |
Precautionary Statements | P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338 |
Hazard Classifications【危险分类】 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
Target Organs【靶器官】 | Respiratory system |
Storage Class Code【储存分类代码】 | 11 - Combustible Solids |
WGK | WGK 3 |
Personal Protective Equipment【个人防护装备】 | dust mask type N95 (US), Eyeshields, Gloves |