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Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)

产品编号:4074667
CAS NO:27057-09-6
包装规格:250 MG,1 G
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品编号包装单位单价(元)国内现货国外库存询价单
4074667250 MG1470
40746671 G3520
产品别名

27057-09-6

Chloro(2-methylphenyl)bis(triphenylphosphine)nickel(II)

[Bis(triphenylphosphine)](o-tolyl)chloronickel

Buchwald Nickel Cross-Coupling Catalyst Precursor

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C43H37ClNiP2
Molecular weight
709.85
PubChem Substance ID【PubChem化学物质编号】
329768436
Application【应用】
Product is a precursor to the synthesis of an air-stable Ni-precatalyst developed by Buchwald and coworkers.
Other Notes【其他说明】
Development of an Air-Stable Nickel Precatalyst for the Amination of Aryl Chlorides, Sulfamates, Mesylates, and Triflates
产品性质
reaction suitability
core: nickel
reagent type: catalyst
Quality Level【质量水平】
100
mp
195-200 ℃
storage temp.【储存温度】
2-8℃
SMILES string
Cl[Ni]C1=CC=CC=C1C.P(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.P(C5=CC=CC=C5)(C6=CC=CC=C6)C7=CC=CC=C7
InChI
1S/2C18H15P.C7H7.ClH.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;/h2*1-15H;2-5H,1H3;1H;/q;;;;+1/p-1
InChI key
QVGJKVLYWZGANE-UHFFFAOYSA-M
packaging【包装】
1 g in glass bottle
250 mg in glass bottle
安全信息
Pictograms【象形图】
GHS07,GHS08
Signal word【警示用语:】
Danger
Hazard Statements
H317 - H350
Precautionary Statements
P201 - P280 - P302 + P352 - P308 + P313
Hazard Classifications【危险分类】
Carc. 1B - Skin Sens. 1
Storage Class Code【储存分类代码】
6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGK
WGK 3
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