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Thianthrene S-oxide
产品别名
2362-50-7
Thianthrene S-oxide
Non-fluorinated sulfoxide-based thianthrene reagent
Thianthrene 5-oxide
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C12H8OS2 |
| Molecular weight | 232.32 |
| MDL number | MFCD01464038 |
| Application【应用】 | Thianthrene S-oxide is a sulfoxide-based thianthrene reagent for late-stage C-H functionalization. Developed by the Ritter Lab, C-H functionalization by thianthrenation proceeds with >99% selectivity and furnishes functionalized arenes serving as synthetic linchpins for further participation in diverse transformations. Nonfluorinated thianthrene S-oxide is best used for all arenes more electron-rich than anisole. For other arenes, the fluorinated TFT S-oxide (903981) was demonstrated as the thanthrenation reagent. |
| Other Notes【其他说明】 | Site-selective and versatile aromatic C-H functionalization by thianthrenation Video: Site-selective C-H functionalization by thianthrenation In the Pipeline: New Chemistry, Making New Things Ti(Phen)(OC2H5)2Cl2: a highly efficient pre-?catalyst for selective oxidation of organic sulfides to sulfoxides by hydrogen peroxide |
| Legal Information【法律信息】 | Patent Application EP18204755.5 This product is manufactured pursuant to a license with Studiengesellschaft Kohle mbH |
产品性质
| Assay【测定】 | ≥95% |
| form【形式】 | powder |
| storage temp.【储存温度】 | 2-8℃ |
| InChI | 1S/C12H8OS2/c13-15-11-7-3-1-5-9(11)14-10-6-2-4-8-12(10)15/h1-8H |
| InChI key | NYVGTLXTOJKHJN-UHFFFAOYSA-N |
安全信息
| Storage Class Code【储存分类代码】 | 13 - Non Combustible Solids |
| WGK | WGK 3 |
