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2-Bromo-6-(trimethylsilyl)phenyl triflate
产品别名
1092542-31-8
2-Bromo-6-(trimethylsilyl)phenyl triflate
Garg 3-Bromobenzyne Precursor
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C10H12BrF3O3SSi |
| Molecular weight | 377.25 |
| PubChem Substance ID【PubChem化学物质编号】 | 329768639 |
| NACRES | NA.22 |
| Application【应用】 | Bromosilyltriflate has been shown to be a useful precursor for the generation of a bromobenzyne intermediate. The bromobenzyne intermediate can be generated in the presence of cesium or potassium fluoride and can be trapped with various dipolariphiles. Synchronous Ar-F and Ar-Sn Bond Formation Through Fluorostannylation of Arynes Continuous-Flow Synthesis of Trimethylsilylphenyl Perfluorosulfonate Benzyne Precursors |
产品性质
| Quality Level【质量水平】 | 100 |
| Assay【测定】 | 95% |
| form【形式】 | liquid |
| refractive index【折射率】 | n |
| density | 1.482 g/L at 25 ℃ |
| storage temp.【储存温度】 | 2-8℃ |
| SMILES string | O=S(OC1=C([Si](C)(C)C)C=CC=C1Br)(C(F)(F)F)=O |
| InChI | 1S/C10H12BrF3O3SSi/c1-19(2,3)8-6-4-5-7(11)9(8)17-18(15,16)10(12,13)14/h4-6H,1-3H3 |
| InChI key | ZNKAHJCGEPVEBA-UHFFFAOYSA-N |
| packaging【包装】 | 1 g in glass bottle 250 mg in glass bottle |
安全信息
| Pictograms【象形图】 | GHS05 |
| Signal word【警示用语：】 | Danger |
| Hazard Statements | H314 |
| Precautionary Statements | P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 - P405 |
| Hazard Classifications【危险分类】 | Eye Dam. 1 - Skin Corr. 1B |
| Storage Class Code【储存分类代码】 | 8A - Combustible, corrosive hazardous materials |
| WGK | WGK 3 |
