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(2R)-2-Phenyl-3,4-dihydro-2H-pyrimido[2,1-b][1,3]benzothiazole
产品别名
1316861-19-4
(2R)-2-Phenyl-3,4-dihydro-2H-pyrimido[2,1-b][1,3]benzothiazole
(R)-Homobenzotetramisole
(R)-2-Phenyl-3,4-dihydro-2H-benzo[4,5]thiazolo[3,2-a]pyrimidine
Birman (R)-HBTM
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C16H14N2S |
| Molecular weight | 266.36 |
| MDL number | MFCD26793803 |
| Application【应用】 | This chiral isothiourea homobenzotetramisole ((R)-HBTM) developed by the Birman lab is an organocatalyst that has been used for kinetic resolution, determination of absolute configuration, and nucleophile-catalysed, Michael–aldol-b-lactonization (NCMAL). This same product was previously listed as L511730, and the complementary (S)-HBTM organocatalyst (900542) is also available. |
| Other Notes【其他说明】 | Technology Spotlight: Homobenzotetramisole (HBTM): A General Organocatalyst for Asymmetric Acylations [1] Determination of the Absolute Configuration β-Chiral Primary Alcohols Using the Competing Enantioselective Conversion Method [2] Asymmetric Catalytic Synthesis of Thiochromenes via an Acyl Transfer-Initiated Cascade [3] Rapid assembly of complex cyclopentanes employing chiral, α, β-unsaturated acylammonium intermediates [4] Determination of Absolute Configuration Using Kinetic Resolution Catalysts [5] Kinetic Resolution of Secondary Alcohols Using Amidine-Based Catalysts |
产品性质
| Quality Level【质量水平】 | 100 |
| Assay【测定】 | ≥95% |
| form【形式】 | powder or chunks |
| mp | 145-147 ℃ |
| storage temp.【储存温度】 | 2-8℃ |
| SMILES string | C12=CC=CC=C1SC3=N[C@@H](C4=CC=CC=C4)CCN23 |
| InChI | 1S/C16H14N2S/c1-2-6-12(7-3-1)13-10-11-18-14-8-4-5-9-15(14)19-16(18)17-13/h1-9,13H,10-11H2/t13-/m1/s1 |
| InChI key | ZMYZJAQMQBHNLH-CYBMUJFWSA-N |
安全信息
| Storage Class Code【储存分类代码】 | 13 - Non Combustible Solids |
| WGK | WGK 3 |
