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(CyPAd-DalPhos)NiCl(otol)
产品别名
2115838-60-1
(CyPAd-DalPhos)NiCl(otol)
8-(2-(Dicyclohexylphosphaneyl)phenyl)-1,3,5,7-tetramethyl-2,4,6-trioxa-8-phosphaadamantane nickel(II) o-tolyl chloride
结构式
基本信息
Empirical Formula【经验(实验)分子式】 | C35H49ClNiO3P2 |
Molecular weight | 673.86 |
Application【应用】 | (CyPAd-DalPhos)NiCl(otol) is an air stable precatalyst developed in the Stradiotto lab used for C(sp2)-O coupling and N-arylation reactions. |
Other Notes【其他说明】 | Technology Spotlight: DalPhos ligands Exploiting Ancillary Ligation To Enable Nickel-Catalyzed C–O Cross-Couplings of Aryl Electrophiles with Aliphatic Alcohols Nickel-Catalyzed N-Arylation of Cyclopropylamine and Related Ammonium Salts with (Hetero)aryl (Pseudo)halides at Room Temperature |
产品性质
Assay【测定】 | ≥95% |
form【形式】 | powder |
mp | 193-197 ℃ |
安全信息
Pictograms【象形图】 | GHS07,GHS08,GHS09 |
Signal word【警示用语:】 | Danger |
Hazard Statements | H302 + H312 + H332 - H341 - H351 - H372 - H410 |
Precautionary Statements | P201 - P273 - P280 - P302 + P352 + P312 - P304 + P340 + P312 - P308 + P313 |
Hazard Classifications【危险分类】 | Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 Inhalation - Muta. 2 - STOT RE 1 Inhalation |
Storage Class Code【储存分类代码】 | 6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects |
WGK | WGK 3 |