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cis-[2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl](2-methylphenyl)nickel(II) chloride
产品别名
1594113-05-9
cis-[2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl](2-methylphenyl)nickel(II) chloride
cis-((S)-BINAP)Ni(o-tolyl)Cl
结构式
基本信息
| Empirical Formula【经验(实验)分子式】 | C51H39ClNiP2 |
| Molecular weight | 807.95 |
| Application【应用】 | The following Ni-complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)2, however, this precatalyst will not require any glovebox or schlenk techniques that must be followed with Ni(cod)2. Rates are enhanced and selectivity is maintained when compared to the same reaction with Ni(cod)2. |
| Other Notes【其他说明】 |
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| Legal Information【法律信息】 | Patent application PCT/US2014/064565. Sold under license from the Massachusetts Institute of Technology. |
产品性质
| Quality Level【质量水平】 | 100 |
| form【形式】 | powder or solid |
| reaction suitability | core: nickel reagent type: catalyst |
| mp | >300 ℃ |
| SMILES string | Cl[Ni]1(P(C2=C([H])C([H])=C([H])C([H])=C2[H])(C3=C([H])C([H])=C([H])C([H])=C3[H])C(C([H])=C4[H])=[C@@]([C@@]5=C(P1(C6=C([H])C([H])=C([H])C([H])=C6[H])C7=C([H])C([H])=C([H])C([H])=C7[H])C([H])=C([H])C8=C5C([H])=C([H])C([H])=C8[H])C9=C4C([H])=C([H])C([H])=C |
安全信息
| Storage Class Code【储存分类代码】 | 4.1B - Flammable solid hazardous materials |
| WGK | WGK 3 |
