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SLAP N-Bn Pip Reagent

产品编号:4151564
规格:95%
CAS NO:1908469-38-4
包装规格:500 MG
产品类别:进口试剂
品牌:Sigma-Aldrich
优惠价:立即咨询
产品价格
产品编号包装单位单价(元)国内现货国外库存询价单
4151564500 MG1000
产品别名

1908469-38-4

SLAP N-Bn Pip Reagent

N1-Benzyl-N1-((trimethylsilyl)methyl)ethane-1,2-diamine

结构式
基本信息
Empirical Formula【经验(实验)分子式】
C13H24N2Si
Molecular weight
236.43
PubChem Substance ID【PubChem化学物质编号】
329769827
NACRES
NA.22
Application【应用】
Silicon amine protocol (SLAP) reagents, in conjunction with aldehydes and ketones, form N-unprotected piperazines via photocatalytic cross-coupling with Ir[(ppy)2dtbbpy]PF6 (747769). Heteroaromatic, aromatic, and aliphatic aldehydes are well tolerated, as are structurally and stereochemically complex SLAP reagents. This product was introduced in collaboration with the Bode Research Group and provides a tin-free alternative to SnAP (tin amine protocol) reagents for piperazine synthesis.
Other Notes【其他说明】
  • Technology Spotlight: SLAP Reagents for Piperazine Synthesis
  • Silicon Amine Reagents for the Photocatalytic Synthesis of Piperazines from Aldehydes and Ketones
  • Lewis Acid Induced Toggle from Ir(II) to Ir(IV) Pathways in Photocatalytic Reactions: Synthesis of Thiomorpholines and Thiazepanes from Aldehydes and SLAP Reagents.
  • Continuous Flow Synthesis of Morpholines and Oxazepanes with Silicon Amine Protocol (SLAP) Reagents and Lewis Acid Facilitated Photoredox Catalysis
产品性质
Quality Level【质量水平】
100
Assay【测定】
95%
form【形式】
liquid (paste)
refractive index【折射率】
n/D 1.5071
density
0.9366 g/mL
storage temp.【储存温度】
−20℃
packaging【包装】
500 mg in glass bottle
安全信息
Pictograms【象形图】
GHS07
Signal word【警示用语:】
Warning
Hazard Statements
H315 - H319 - H335
Precautionary Statements
P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
Hazard Classifications【危险分类】
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs【靶器官】
Respiratory system
Storage Class Code【储存分类代码】
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)【闪点(F)】
198.0 °F
Flash Point(C)【闪点(C)】
92.2 ℃
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