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广州伟伯科技有限公司

广州伟伯科技有限公司

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产品中心

SLAP N-Bn-3Me-Pip Reagent

产品编号：

4151565

CAS NO：

包装规格：

500 MG

产品类别：

进口试剂

品牌：	Sigma-Aldrich

优惠价：

产品价格

产品编号	包装单位	单价(元)	国内现货	国外库存	询价单
4151565	500 MG	1039

产品别名

2168413-62-3

SLAP N-Bn-3Me-Pip Reagent

(S)-N1-Benzyl-N1-((trimethylsilyl)methyl)propane-1,2-diamine

结构式

基本信息

Empirical Formula【经验(实验)分子式】	C₁₄H₂₆N₂Si
Molecular weight	250.46
Application【应用】	Silicon amine protocol (SLAP) reagents, in conjunction with aldehydes and ketones, form N-unprotected piperazines via photocatalytic cross-coupling with Ir[(ppy)₂dtbbpy]PF₆ (747769). Heteroaromatic, aromatic, and aliphatic aldehydes are well tolerated, as are structurally and stereochemically complex SLAP reagents. This product was introduced in collaboration with the Bode Research Group and provides a tin-free alternative to SnAP (tin amine protocol) reagents for piperazine synthesis.
Other Notes【其他说明】	Technology Spotlight: SLAP Reagents for Piperazine Synthesis Silicon Amine Reagents for the Photocatalytic Synthesis of Piperazines from Aldehydes and Ketones Lewis Acid Induced Toggle from Ir(II) to Ir(IV) Pathways in Photocatalytic Reactions: Synthesis of Thiomorpholines and Thiazepanes from Aldehydes and SLAP Reagents. Continuous Flow Synthesis of Morpholines and Oxazepanes with Silicon Amine Protocol (SLAP) Reagents and Lewis Acid Facilitated Photoredox Catalysis

产品性质

Quality Level【质量水平】	100
storage temp.【储存温度】	−20℃
packaging【包装】	500 mg in amber glass bottle

安全信息

Pictograms【象形图】	GHS07
Signal word【警示用语：】	Warning
Hazard Statements	H315 - H319 - H335
Precautionary Statements	P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
Hazard Classifications【危险分类】	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs【靶器官】	Respiratory system
Storage Class Code【储存分类代码】	10 - Combustible liquids
WGK	WGK 3

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